连续管焊缝在CO2环境下电化学腐蚀行为实验研究

    Experimental Study of Electrochemical Corrosion Behavior of Coiled Tubing Welding Seam in CO2 Environment

    • 摘要: 在气田开采过程中,CO2电化学腐蚀是导致连续管失效的主要原因之一。为获得连续管焊缝处和母材在CO2环境下的腐蚀规律,利用电化学工作站和电热恒温水浴锅实验测试CT110连续管母材和焊缝的动电位极化曲线和电化学阻抗谱,研究其在模拟CO2气田采出液中的电化学腐蚀行为。结果表明:连续管母材和焊缝试样的极化曲线呈现典型阳极溶解特征,腐蚀过程受阴极控制。母材和焊缝在饱和CO2溶液较无CO2条件下耐腐蚀性能更低。在饱和CO2条件下,随着温度的增加,母材和焊缝的腐蚀电位减小,腐蚀电流密度增大,极化电阻减小,耐腐蚀性能减弱。与母材相比,焊缝腐蚀电位和极化电阻较低,腐蚀电流密度较高,耐腐蚀性能低于母材。

       

      Abstract: CO2 electrochemical corrosion is one of the main reasons for the failure of coiled tubing(CT) in gas field exploitation. In order to obtain the corrosion law of CT weld and base material in CO2 environment, the electrochemical corrosion of CT110 base material and weld samples in CO2 simulated gas field environment was studied by electrochemical workstation and electrothermal thermostatic water bath by electrodynamic polarization curve and electrochemical impedance spectroscopy tests. The results show that the polarization curves of the CT base material and the weld samples show typical characteristics of anode dissolution, and the corrosion process is controlled by the cathode. The corrosion resistance of base material and weld in saturated CO2 solution is weaker than that without CO2. Under the condition of saturated CO2, with the increase of temperature, the corrosion potential of base metal and weld decreases, the corrosion current density increases, the polarization resistance decreases and the corrosion resistance weakens. Compared with those of the base metal, the corrosion potential and polarization resistance of the weld are lower and the corrosion current density is higher, indicating that the corrosion resistance is lower than that of the base metal.

       

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