主合金成分对铝合金中析出相的影响

    Effect of Main Alloy Composition on Equilibrium Phases of Al Alloys

    • 摘要: 利用JMat-Pro软件包对Al-(6.0-8.0)Zn-(1.8-2.8)Mg-(1.4-2.6)Cu合金的热力学相关物理参数和平衡相析出进行了分析。结果表明:合金元素Zn、Mg、Cu、Fe、Si、Zr的偏摩尔吉布斯自由能均为负值。合金中Zn、Mg和Si活度的最大值分别为:0.2、0.061和0.069,Cu、Fe和Zr元素的活度都接近于0。平衡析出相η相、S相和T相的析出起始温度分别为407~443℃、405~473℃和111~176℃。η相析出量随Zn含量的增加而增加,随Cu含量的增加而减少。S相析出量随Cu含量的增加而增加,随Zn含量的增加而减少。T相析出量随Mg含量的增加而增加,随Zn、Cu含量的增加而减少。

       

      Abstract: The thermodynamics-dependent physics parameters and equilibrium phases precipitation of Al-(6.0-8.0) Zn-(1.8-2.8) Mg-(1.4-2.6) Cu alloys were analyzed by using software package JMat-Pro for material property simulation of Al-base alloys. The resuls show that the partial Gibbs free energy of alloy elements Zn, Mg, Cu, Fe, Si and Zr are all negative. The maximum activities of Zn, Mg and Si are 0.2, 0.061 and 0.069, respectively.The activities of Cu, Fe and Zr closes to 0. The start temperature of η, S and T phases precipitation are in the temperature range of (407-443 ℃), (405-473 ℃) and (111-176℃), respectively.The amount of η phase precipitation increases as the contents of Zn increases, whereas decreases as the content of Cu increases. The amount of S phase precipitation increases as the content of Cu increases, whereas decreases as the content of Zn increases.The amount of T phase precipitation increases as the content of Mg increases, whereas decreases as the content of Zn and Cu increases.

       

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