超音速火焰喷涂WC基金属陶瓷涂层的长期腐蚀行为

    Long-term Corrosion Behavior of WC-based Cermet Coatings by HVOF Spraying

    • 摘要: 采用超音速火焰喷涂技术在Q235钢基体上制备了WC-Ni和WC-Cr3C2-Ni两种涂层。利用X射线衍射仪、金相显微镜等分析了涂层的相组成和组织结构;通过电化学工作站、全浸泡试验等研究涂层在3.5 wt%NaCl溶液中的耐腐蚀性。结果表明:两种涂层结构均匀致密,WC-Ni和WC-Cr3C2-Ni涂层的孔隙率分别为1.71%和1.15%。在3.5wt%NaCl溶液中,两种涂层均产生钝化现象,涂层表面的钝化膜提高了其耐腐蚀能力。在3.5wt%NaCl溶液中的长期浸泡腐蚀过程中,WC-Cr3C2-Ni涂层的失重少于WC-Ni涂层,其耐腐蚀性能更好。浸泡28 d后,WC-Ni涂层表面结构较疏松,孔洞较小但比较密集;WC-Cr3C2-Ni涂层表面较平整,孔洞较大但分布稀疏。疏松的结构、较高的孔隙率会导致侵蚀性离子渗入到涂层的孔隙和晶界中,从而降低涂层的耐腐蚀性。

       

      Abstract: WC-Ni and WC-Cr3C2-Ni coatings were prepared on Q235 steel substrate by HVOF spraying technology.X-ray diffractometer and metallurgical microscope were used to analyze the phase composition and structure of the coatings.The corrosion resistance of the coatings in 3.5wt% NaCl solution was studied by electrochemical workstation and full immersion experiment. The results show that the two coatings have uniform and dense structures, and the porosities of the WC-Ni and WC-Cr3C2-Ni coatings were respectively 1.71% and 1.15%. In the 3.5wt% NaCl solution, both coatings produce passivation, and the passivation film on the coating surface improve the corrosion resistance. During the long-term immersion corrosion process in 3.5wt% NaCl solution, the wear mass loss of the WC-Cr3C2-Ni coating is less than that of WC-Ni coating,implying that the corrosion resistance of the WC-Cr3C2-Ni coating is better than that of the WC-Ni coating. After being immersed for 28 d, the surface structure of the WC-Ni coating is relatively loose with small and densely distributed pores,while the surface of the WC-Cr3C2-Ni coating is relatively flat with large and sparsely distributed pores. The loose structure and high porosity cause corrosive ions to penetrate into the pores and grain boundaries of the coatings, then,the corrosion resistance of the coatings reduces.

       

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