感应熔覆过程中氧化皮对锅炉管内壁力学性能的影响及其抑制技术研究

    Research on Influence of Oxide Scale on Mechanical Properties of Inner Wall of Boiler Tube and Its Suppression Technology in Process of Induction Cladding

    • 摘要: 高频感应熔焊技术代表了锅炉四管受热面高温防腐技术的发展方向。但由于高频感应线圈对管外壁涂层加热重熔时,管内壁也随之被加热,使管内壁表面产生氧化皮。通过检测表面硬度和脱碳层深度等指标,对于氧化皮对管内壁性能的影响进行了评估。结果表明:当重熔温度升高使得管内壁温度超过580℃时,由管内壁基体表面起向外依次排列为FeO、Fe3O4、Fe2O3等三层氧化膜,厚度比约为1∶10∶100。FeO虽然较薄但结构疏松,晶格缺陷多,不稳定易分解,易从管内壁表面脱落,是造成爆管事故的主要因素。利用氮气保护的方法对感应重熔过程产生的氧化皮进行了有效抑制,该方法也抑制了管排背面氧化皮的产生,实验证明其效果显著。

       

      Abstract: High-frequency induction cladding technology is one of the main directions for the development of high-temperature anti-corrosion technology for the four heating surfaces of boilers. However, when the high-frequency induction coil heats the coating on the outer wall of the tube, the inner wall of the tube is also heated, causing oxide scale on the surface of the inner wall of the tube.By testing the surface hardness and the depth of the decarburized layer, the influence of the oxide scale on the performance of the inner wall of the tube was evaluated.The results show that when the temperature of the inner wall of the tube exceeds 580 ℃, three oxide films of FeO, Fe3O4 and Fe2O3 are sequentially formed from the surface of the inner wall of the tube to the outside, with a thickness ratio of about 1∶10∶100.Although FeO is thin, it has a loose structure, a crystal lattice with many defects, and is unstable and easy to decompose, so it is easy to fall off from the inner wall surface of the tube, which is the main factor causing the tube burst accident. The method of nitrogen protection is used to effectively suppress the generation of oxide scale during the induction cladding process. This method also suppresses the generation of oxide scale on the back of the tube row, and the experiment proves that its effect is significant.

       

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