J55套管钢CO2和微生物腐蚀行为的研究

    Study on CO2 and Microbial Corrosion Behavior of J55 Casing Steel

    • 摘要: 通过模拟井下环境的均匀和局部腐蚀试验,结合电化学测试分析,研究了J55 套管钢的腐蚀行为和腐蚀机理。结果表明:随着温度的升高,J55 套管钢的CO2 均匀腐蚀速率逐渐增大,当温度达到60 ℃时,其腐蚀速率达到最大值,即1.0175 mm/a,并且局部腐蚀最为严重。SRB、TGB 导致J55 套管钢的均匀腐蚀速率明显增大,局部腐蚀程度显著增强。在单独CO2 腐蚀环境中,J55 套管钢的阴极和阳极均表现为活化反应,自腐蚀电位下的腐蚀电流密度为阴极反应过程所控制。随着温度的升高,其电化学腐蚀热力学趋势增强,当温度达到60 ℃时,J55 套管钢动力学阻力达到极小值点,自腐蚀电流密度最大。SRB、TGB 使J55 钢在CO2 腐蚀环境中的自腐蚀电位明显降低,并显著促进了CO2 腐蚀的阴极氢去极化过程,导致J55 钢的阳极溶解加速。

       

      Abstract: The corrosion behavior and mechanism of J55 casing steel were studied through uniform and local corrosion tests in simulated downhole environment and electrochemical test analysis.The results show that the CO2 uniform corrosion rate of J55 casing steel increases gradually with the increase of temperature.When the temperature reaches 60 ℃, the corrosion rate reaches the maximum value of 1.0175 mm/a, and the local corrosion is the most serious.SRB and TGB significantly increase the uniform corrosion rate and local corrosion degree of J55 casing steel.In CO2 corrosion environment, both the cathode and anode of J55 casing steel show activation reaction, and the corrosion current density under self-corrosion potential is controlled by the cathodic reaction process.When the temperature reaches 60 ℃, the dynamic resistance of J55 casing steel reaches the minimum value and the self-corrosion current density reaches the maximum value.SRB and TGB significantly reduce the self-corrosion potential of J55 steel in CO2 corrosion environment, while can promote the cathodic hydrogen depolarization process of CO2 corrosion, so the anodic dissolution of J55 steel is accelerated.

       

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