多级断续时效对固溶处理7B04铝合金抗剥落腐蚀行为的影响

    Effect of Multi-step Interrupted Aging on Exfoliation Corrosion Behavior of Solution Heat-treated 7B04 Al Alloy

    • 摘要: 采用硬度测试、电导率测试、剥落腐蚀试验测试和透射电镜TEM观测等方式研究断续时效制度对固溶处理的7B04铝合金板材抗剥落腐蚀性能的影响。结果表明:与双级时效铝合金7B04相比,多级断续时效处理在基本保持合金硬度和电导率的同时,提升了合金的抗剥落腐蚀能力。第一级时效过程后,其晶界处存在细小且连续分布的点状析出相;第二级低温时效过程后,材料微观组织未出现明显的η相析出特征;第三级160℃时效过程中,棒状η相在晶界处析出长大,逐渐呈断续分布形貌。该阶段对硬度、电导率影响显著。随着时间的延长,硬度在160℃时效1~4 h升至峰值后下降。本研究中固溶淬火态7B04铝合金的最佳断续时效制度为120℃×10 h+自然时效10 d (25℃×240 h)+160℃×18 h,在该工艺条件下,材料的硬度、电导率、48 h剥落腐蚀试评级分别为160.6 HV0.1、21.7 MS/m、EB-。

       

      Abstract: The effect of interrupted aging on the exfoliation corrosion susceptibility of solution heat-treated 7B04 aluminum alloy plates was investigated through hardness tests, electrical conductivity tests, exfoliation corrosion tests and transmission electron microscopy. The results show that compared with the two-step aged 7B04 aluminum alloy, the multi-stage interrupted aging treatment can maintain the alloy’s hardness and electrical conductivity while improving the capability of exfoliation corrosion resistance of the alloy. After the first-stage aging process, the grain boundary precipitates are fine and continuously distributed dot-like precipitates. After second-stage low-temperature aging process, the microstructure does not show prominent η phase precipitation characteristics. During the third aging process at 160 ℃, the rod-shaped η phase appears and coarsens at the grain boundary, showing a discontinuous distribution morphology. As a result,the electrical conductivity of 7B04 alloy has a moderate increase while the hardness rises to the peak after aging at 160 ℃ for 1-4 h and then gradually decreases. The optimal parameters in the study is two-step aged by 120 ℃×10 h+natural aging 10 d+160 ℃×18h. Under the condition, the hardness, electrical conductivity and exfoliation corrosion resistance level of 7B04aluminum alloy are 160.6 HV0.1, 21.7 MS/m and EB-, respectively.

       

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