ZTC4钛合金铸件在人工海水中的电偶腐蚀行为

    Galvanic Corrosion Behavior of ZTC4 Titanium Alloy Castings in Artificial Seawater

    • 摘要: 钛合金铸件在铸造过程中不可避免的产生夹渣、气孔和缩孔等内部缺陷,在缺陷挖除后采用TIG 焊修复,形成与母材相异的焊接和热影响区组织。从ZTC4 钛合金铸件的母材、焊接和热影响区等部位切取偶联试样和对比试样,在人工海水中进行电偶腐蚀和全浸腐蚀试验,测量电偶电流、腐蚀电位以及失重和腐蚀速率,同时进行金相组织和表面氧化层检测。结果表明,ZTC4 钛合金铸件母材、焊接及热影响区的组织和表面氧化层厚度有较大差异,腐蚀电位相近,电偶电流接近0,失重和腐蚀速率很小,相互之间无明显电偶腐蚀倾向,具有良好的耐腐蚀性;表面粗糙度不影响腐蚀电位和腐蚀速率;表面氧化层具有较强钝化和自愈能力,遭破坏后可迅速修复,无明显腐蚀迹象。

       

      Abstract: During the casting process, titanium alloy castings inevitably have internal defects such as slag inclusion, porosity and shrinkage cavity.After the defects were removed, TIG welding was used to repair them, forming the structure of welding and heat affected zone different from the base metal.The coupling samples and comparison samples were cut from the base metal, welding and heat affected zone of ZTC4 titanium alloy castings.The galvanic corrosion and full immersion corrosion tests were carried out in artificial seawater.The galvanic current, corrosion potential, weight loss and corrosion rate were measured, and the metallographic structure and surface oxide layer were detected.The results show that the microstructure and surface oxide layer thickness of base metal, welding and heat affected zone of ZTC4 titanium alloy casting are quite different, the corrosion potential is similar, the galvanic current is close to 0, the weight loss and corrosion rate are very small, and there is no obvious galvanic corrosion tendency between them, and it has good corrosion resistance.Surface roughness has no effects on the corrosion potential and corrosion rate.The surface oxide layer has strong passivation and self-healing ability, which can be quickly repaired after being damaged without obvious corrosion signs.

       

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