稀土Ce对铝用TiC细化剂细化效果的影响

    Effect of Rare Earth Ce on Refining Effect of TiC Refiner for Aluminum

    • 摘要: 以工业纯铝和5μm的TiC粉末及稀土Ce为原料,采用金属型模具浇注并通过调控TiC和Ce的含量制备了铝铸锭。采用OM、SEM进行组织观察,并进行致密度、电导率、显微硬度的测试。结果表明:当TiC的加入量为0.1%、0.2%、0.3%和0.4%时,Ce的最佳添加量分别为0.4%、0.4%、0.3%和0.3%,所制备铸锭的晶粒尺寸较原始样品分别降低1.71、1.50、1.26和1.31倍;所制备样品的致密度和显微硬度均得到了提高,致密度达99%以上,显微硬度高达144.6 HV,较原始样品分别提高了16%和44.3%,而电导率无明显下降;TiC和Ce的最佳添加量分别为0.1%和0.4%,此时稀土形成了稀土化合物,促进了TiC的细化效果。

       

      Abstract: Using industrial pure aluminum, 5 μm TiC powder and rare earth Ce as raw materials, aluminum ingots were prepared by casting in a metal mold and adjusting the contents of TiC and Ce. The microstructure was observed by OM and SEM, and the density, electrical conductivity and microhardness were tested. The results show that when the addition amount of TiC is 0.1%, 0.2%, 0.3% and 0.4%, the optimal amount of Ce is 0.4%, 0.4%, 0.3% and 0.3%, respectively. Compared to the grain size of the samples without TiC and Ce, that of the samples with TiC and Ce is decreased by 1.71, 1.50, 1.26 and 1.31 times, respectively. The relative densities and microhardness of the prepared samples are improved, with the relative density of more than 99%, and the microhardness is up to 144.6 HV, which is increased by 16% and 44.3% compared with the original samples, respectively. Meanwhile, the electrical conductivities have a little change. The optimal addition amount of TiC and Ce is 0.1% and 0.4%, respectively. At the time, rare earth forms rare earth compounds, which promotes the refining effect of TiC.

       

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