Y元素对铸态Mg-Al-Ca-Mn合金组织与耐腐蚀性能的影响

    Effects of Y Element on Microstructure and Corrosion Resistance of As-Cast Mg-Al-Ca-Mn-Y Alloy

    • 摘要: 采用金相显微镜、扫描电镜、XRD分析、腐蚀试验和电化学测试等研究了Mg-4Al-3Ca-0.7Mn-xY(x=0、0.8、1.5)铸态合金的微观组织与耐腐蚀性能。结果表明:未添加Y的Mg-4Al-3Ca-0.7Mn合金组织由α-Mg、Al2Ca相、Mg2Ca相组成。添加0.8wt% Y后,合金组织中晶粒得到明显细化,析出相变得细小,Al2Ca相、Mg2Ca相数量减少,并有Al2Y相生成。Y含量增加到1.5wt%时,合金晶粒细化效果不明显,大量Al2Y相聚集在晶界处呈网状分布。添加适量的Y可提高Mg-4Al-3Ca-0.7Mn-xY合金的耐腐蚀性,Y添加量为0.8wt%时,该合金的耐腐蚀性最佳。

       

      Abstract: The microstructure and corrosion resistance of as-cast Mg-4Al-3Ca-0.7Mn-xY (x=0, 0.8, 1.5) alloys were investigated by metallographic microscope, scanning electron microscope, XRD, corrosion test and electrochemical test.The results show that the microstructure of Mg-4Al-3Ca-0.7Mn alloy without Y is composed of α-Mg, Al2Ca and Mg2Ca phases.After adding 0.8wt%Y, the grains in the microstructure of the alloy are obviously refined, and the precipitation phase is fine.The number of Al2Ca and Mg2Ca phases is reduced, and the Al2Y phase is formed.When Y content increases to 1.5wt%, the grain refinement effect is not obvious, and a large amount of Al2Y phase aggregate in a network distribution at grain boundaries.The corrosion resistance of Mg-4Al-3Ca-0.7Mn-xY alloy can be improved by adding appropriate Y element.The corrosion resistance of the alloy is best when the addition amount of Y is 0.8wt%.

       

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