钨极电弧熔覆FeCrMnCuNiSi1高熵粉芯焊丝涂层的组织与性能

    Microstructure and Properties of FeCrMnCuNiSi1 High Entropy Core Wire Coating by Tungsten Electrode Arc Melting

    • 摘要: 采用粉芯焊丝成型设备拉拔高熵成分的粉芯焊丝,通过钨极电弧熔覆制备了FeCrMnCuNiSi1高熵合金。研究了微观组织、力学性能和电化学腐蚀性能。结果表明,FeCrMnCuNiSi1表现出等轴晶和细化柱状晶混合态,其物相主要为BCC(面心立方)和FCC(体心立方)。显微硬度可达518.88 HV,平均显微硬度为基材的3倍以上;磨损率仅为3.80×10-6mm3/(N·mm),不足基材磨损率的1/4。涂层的自腐蚀电位明显大于基材的自腐蚀电位,自腐蚀电流约为基材的60%,具备良好的耐腐蚀性能。实验使用的粉芯焊丝是通过常规粉芯焊丝成型设备生产的,生产价格接近常规焊丝,且性能优越,因此该方法有利于为实用性的高熵涂层开发、制备和应用提供重要依据。

       

      Abstract: The powder cored wire of high entropy composition was drawn by powder cored wire forming, equipment and FeCrMnCuNiSi1 high-entropy alloy was prepared by tungsten arc fusion. The microstructure, mechanical properties, and electrochemical corrosion properties of FeCrMnCuNiSi1 were investigated. The results show that FeCrMnCuNiSi1 exhibits a mixture of equiaxed and refined columnar crystal states, and its physical phases are mainly BCC(face-centered cubic) and FCC(body-centered cubic). The microhardness of the coating is 518.88 HV, which is more than 3 times that of the base material. The wear rate is only 3.80 ×10-6mm3/(N·mm), which is less than 1/4 of the wear rate of the base material. The self-corrosion potential of the coating is significantly higher than that of the base material, and the self-corrosion current is about 60% of that of the base material, which has good corrosion resistance. The experimentally used powder cored wire is produced by conventional powder cored wire forming equipment, and the production price is close to that of conventional wire with superior performance, so the method is beneficial to provide an important basis for practical high-entropy coating development, preparation and application.

       

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