含氧化膜钛合金裂纹尖端氢扩散分析

    Hydrogen Diffusion Analysis of Crack Tip of Titanium Oxide Alloy

    • 摘要: 基于扩散和应力耦合的质量平衡方程,建立了外界环境氢渗入覆盖TiO2裂尖并扩散的数学模型。通过在COMSOL中采用有限元法构建具有钝化裂纹尖端的平板计算模型,讨论了氧化膜厚度和裂尖应力状态对氢扩散的影响。结果表明,裂尖氢渗入与扩散受到氧化膜的引入和厚度增加的抑制,外载荷增加会抑制环境中的氢向裂尖渗入,并减少了裂尖的氢富集。应力梯度引起的裂尖氢扩散效果在低浓度时更显著。

       

      Abstract: Models that describing hydrogen permeation through a thin TiO2 film covering on crack tip were developed based on a mass-balance equation consisting of diffusion and the stress state. The models were numerically simulated with a blunting crack tip on plate by finite element method in COMSOL. The effects of oxide film thickness and stress on the diffusion of hydrogen were discussed. The results show that the hydrogen penetrates into the crack tip and diffuses in it are suppressed dramatically by the introduction of film and the increases in thickness. The hydrogen penetration decreases with the increasing applied stress, which relieves the enrichment of hydrogen converged to crack tip. Moreover, the hydrogen diffusion caused by stress gradient is more significant at lower concentration.

       

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