微弧氧化时间对高强镁合金陶瓷层性能的影响

    Effect of Micro-arc Oxidation Time on Microstructure and Properties of Micro-arc Oxidation Ceramic Layer Formed on High Strength Magnesium Alloy

    • 摘要: 采用硅酸盐体系,对不同的微弧氧化时间条件下的高强镁合金进行了微弧氧化处理,并利用数字式涂层测厚仪、SEM、XRD分别对微弧陶瓷层的厚度、陶瓷层以及界面结合情况、微观形貌、陶瓷层元素组成、相组成进行了观察和表征,同时借助Tafel极化曲线研究微弧氧化陶瓷层在3.5% NaCl介质中的电化学腐蚀行为。结果表明:随着微弧氧化时间的延长,陶瓷层的厚度逐渐增加。微弧氧化时间较短时,陶瓷层组织中的孔洞数量较大,孔洞尺寸较小。随着陶瓷层厚度的增加,孔隙率逐渐降低,“火山口”状孔洞的尺寸增加,并且在孔洞间出现了不同程度的微裂纹或网格状裂纹。在5 min微弧氧化时间后形成的陶瓷层主要由MgO、MgSiO3组成,随着氧化时间延长至10、15 min时,陶瓷层中除了MgO、MgSiO3外,还有Mg2SiO4相出现。在质量分数3.5% NaCl溶液中,经微弧氧化处理后,高强镁合金的耐蚀性得到了明显的提高,当微弧氧化时间为15 min时,自腐蚀电流密度较基体降低了2个数量级。

       

      Abstract: Micro-arc oxidation treatment of high strength magnesium alloy with different parameters in silicate system was carried out. The digital coating thickness gauge, SEM, EDS and XRD were used to measure the micro-arc ceramic layer thickness, observe the interface condition layer structure, morphology and characterize the element composition and phase composition. Meanwhile, Tafel polarization curves were used to study the electrochemical corrosion behavior of micro-arc ceramic layer in 3.5% NaCl medium. The results show that the thickness of ceramic layer increases gradually with the prolongation of micro-arc oxidation time. The pore numbers in the ceramic layer is large and the size is small when the oxidation time is short. With the thickness of ceramic layer increasing, the porosity decreases and the size of volcanic crater-shaped pores increase correspondingly, besides micro-cracks or gridded cracks with different degrees appear between the pores. The ceramic layer formed with 5 min micro-arc oxidation is mainly composed of MgO and MgSiO3. Besides MgO and MgSiO3 phases, Mg2SiO4 phase appear in the ceramic layer when the oxidation time is extended to 10 min and 15 min. The corrosion resistance of high-strength magnesium alloy matrix is significantly improved after the micro-arc oxidation treatment in 3.5%wt NaCl solution, and the self-corrosion current density with 15 min micro-arc oxidation treatment decreases by 2 orders than matrix.

       

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