轧制热处理协同调控不锈钢复合板组织及耐蚀性能

    Microstructure and Corrosion Resistance of Stainless Steel Clad Plate Controlled by Rolling Heat Treatment

    • 摘要: 利用埋弧焊与真空电子束焊复合制坯工艺制备了不锈钢/低合金钢复合板,分析了热轧、固溶及回火工艺对复合板基、复材组织及耐蚀性的影响规律。结果表明:复合板经热处理后,元素扩散区域变宽;1100℃固溶后Cr23C6等碳化物固溶于奥氏体晶粒,晶间腐蚀倾向大幅降低;复合板经高温回火处理后,组织由马氏体转变为回火索氏体组织,其中650℃回火工艺下,不锈钢的耐晶间腐蚀性能较热轧态显著提升,电化学腐蚀速率由1.42×10-2mm/a降低到1.14×10-2mm/a。1100℃固溶+650℃回火工艺下复合板具有优异的耐蚀性且界面剪切强度均达到480 MPa,复合板的强度、塑性及韧性均可满足国标要求。

       

      Abstract: The stainless steel/low alloy steel composite plate was prepared by the combined billet making process of submerged arc welding and vacuum electron beam welding. The influence of hot rolling, solution and tempering processes on the composite plate matrix, composite structure and corrosion resistance was analyzed. The results show that after heat treatment, the element diffusion area of the composite plate becomes wider. After solution at 1100 ℃, carbides such as Cr23C6 are dissolved in austenite grains, and the tendency of intergranular corrosion is greatly reduced. After high temperature tempering treatment, the structure of composite plate changed from martensite to tempered sorbite. Under 650 ℃ tempering process, the intergranular corrosion resistance of stainless steel is significantly improved compared with that of hot rolled steel,and the electrochemical corrosion rate is reduced from 1.42×10-2mm/a to 1.14×10-2mm/a. At 1100 ℃ solution and 650 ℃tempering process, the composite plate has excellent corrosion resistance, while the shear strength of the interface reaches 480 MPa. The strength, plasticity and toughness of the composite plate can meet the requirements of the national standard.

       

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