正向电压对SiCp/Al复合材料微弧氧化膜层微观结构及性能的影响

    Effects of Positive Voltage on Microstructure and Properties of Micro-arc Oxidation Films Prepared on SiCp/Al Composite

    • 摘要: 以NaAlO2和NaOH为电解液体系,采用恒压模式在Si Cp/Al复合材料表面制备微弧氧化膜层。通过扫描电子显微镜、X射线衍射仪对膜层微观结构及相组成进行表征,采用划痕仪对膜层结合力进行分析,利用电化学工作站分析耐蚀性。结果表明:在恒压模式下,Si Cp/Al复合材料微弧氧化过程包括钝化及微弧放电、均匀火花放电和弧光放电三个阶段。随着正向电压增加,微弧氧化膜层逐渐变得连续,厚度先增大后减小,正向电压较高时,膜层容易出现微裂纹。正向电压对Si Cp/Al复合材料微弧氧化膜层的物相有一定影响。正向电压为450 V时,制备的膜层与基体结合力达到最大23.55 N。不同正向电压下的微弧氧化均能提高Si Cp/Al复合材料的耐蚀性,正向电压为550 V时,微弧氧化膜层具有优异的耐蚀性。

       

      Abstract: Micro-arc oxidation films were prepared on the surface of SiCp/Al composite using NaAlO2 and NaOH as electrolyte systems in constant voltage. The microstructure and phase composition of the films were characterized by scanning electron microscope(SEM) and X-ray diffraction(XRD). The bonding force of films were analyzed by scratch tester. The corrosion resistance was characterized by electrochemical workstation. The results indicate that the micro-arc oxidation process of SiCp/Al composite includes three stages under the constant voltage mode: passivation and micro-arc discharge,uniform spark and arc discharge. With the increase of positive voltage, the micro-arc oxidation film gradually becomes continuous, and the film thickness increases first and then decreases. When the positive voltage is high, the film is prone to microcracks. Positive voltage has a certain effect on the phase of micro-arc oxidation films on SiCp/Al composite. The maximum bonding force between micro-arc oxidation film and substrate is 23.55 N at 450 V. The corrosion resistance of SiCp/Al composite can be improved by micro-arc oxidation at different positive voltages. The corrosion resistance of the micro-arc oxidation film is excellent when the positive voltage is 550 V.

       

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