等离子熔覆CoCrFeMnNi高熵合金涂层的组织和性能研究

    Study on Microstructure and Properties of Plasma Cladding CoCrFeMnNi High Entropy Alloy Coating

    • 摘要: 通过等离子熔覆技术在E32钢基体上制备了CoFeCrMnNi高熵合金涂层,利用SEM、EDS、XRD等分析涂层的微观组织、相组成、显微硬度和耐腐蚀性,并采用XPS分析涂层钝化膜组成。结果表明,通过等离子熔覆技术制备的CoCrFeMnNi高熵合金涂层与基体达到冶金结合,无裂纹和气孔等缺陷。涂层为简单FCC结构,并呈现出典型枝晶组织。在质量分数3.5%的NaCl溶液中涂层的自腐蚀电位为-0.19 V,自腐蚀电流密度为2.43×10-7A/cm2,腐蚀速率为2.82×10-3mm/a,得益于涂层中Ni、Cr、Co元素生成的致密钝化膜,涂层表现出远超于基体的耐腐蚀性。

       

      Abstract: CoFeCrMnNi high entropy alloy coating was prepared on E32 steel substrate by plasma cladding technology.The microstructure, phase composition, microhardness and corrosion resistance of the coating were analyzed by SEM, EDS and XRD, and the composition of passive film of the coating was analyzed by XPS. The results show that the coating of CoCrFeMnNi high entropy alloy prepared by plasma cladding technology is metallurgically bonded with the substrate, and there are no defects such as cracks and pores. The coating has a simple FCC structure and presents a typical dendritic structure. In 3.5% NaCl solution, the self-corrosion potential of the coating is-0.19 V, the self-corrosion current density is2.43 ×10-7A/cm2, and the corrosion rate is 2.82 ×10-3mm/a. Due to the dense passivation film formed by Ni, Cr and Co elements in the coating, the corrosion resistance of the coating is far superior to that of the substrate.

       

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