Sn-Bi系低温钎料的研究现状与展望

    Research Status and Prospect of Sn-Bi Series Low-temperature Solders

    • 摘要: Sn-Bi系低温钎料合金由于低的熔化温度、较好的润湿性能和较高的抗拉强度,在低温钎焊领域有着较好的前景,是Sb-Pb系钎料合金代替品的有利竞争者。但由于Sn-Bi系钎料合金中Bi相带来的脆性及焊接过程的枝晶偏析和晶粒粗化导致性能下降,很大程度上限制了其使用场景。综述了近年来Sn-Bi钎料的发展动态,阐述了Ag、Cu、Zn、Sb、Ni等5个元素对Sn-Bi钎料的熔化特征、组织结构、力学性能、润湿性以及金属间化合物等方面的影响,指出了不同成分的钎料在目前研究中存在的问题,并展望了今后的研究方向。

       

      Abstract: Due to low melting temperature, good wettability and high tensile strength, Sn-Bi low-temperature solders have a good prospect in the field of low-temperature brazing and they are favorable competitors to become a substitute for Sb-Pb solders. However, the brittleness caused by the Bi phase in the Sn-Bi solders and the degradation of performance due to dendrite segregation and grain coarsening during the welding process largely limit its use scenario. The development of Sn-Bi solders in recent years was reviewed, the influence of five elements such as Ag, Cu, Zn, Sb and Ni on the melting characteristics, microstructure, mechanical properties, wettability, and intermetallic compounds of Sn-Bi solders was described, the problems of different compositions of solders in the current research were pointed out, and the direction of the future research was prospected.

       

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