稀土Gd对Sn-43.5Bi-27Pb合金组织与性能的影响

    Effect of Rare Earth Gd on Microstructure and Properties of Sn-43.5Bi-27Pb Alloy

    • 摘要: 利用扫描电镜(SEM)、差示热分析仪(DTA)、X射线衍射(XRD)等对添加不同Gd含量的Sn-43.5Bi-27Pb合金的微观组织、熔化性能以及力学性能进行了研究。结果表明:Sn-43.5Bi-27Pb合金包含三相,分别为Sn相、Bi相以及Pb7Bi3中间相,其熔点为96.5℃,抗拉强度为55 MPa、伸长率为52.1%。Sn-43.5Bi-27Pb-xGd(x=0.2、0.5、1.0和4.0)合金的抗拉强度都略低于Sn-43.5Bi-27Pb低熔点合金,x=0.2时合金与Sn-43.5Bi-27Pb合金的相组成相同,x=0.5和x=1.0时合金多了Gd相,x=4.0时合金多了Gd和Bi3Gd5相。随着Gd含量增加,熔化区间逐渐缩小,当Gd含量为1.0wt%时,合金的组织与性能最好,其熔化区间最小,为12.72℃,相比于Sn-43.5Bi-27Pb合金降低了2.48℃,其抗拉强度、伸长率和显微硬度分别为49 MPa、47.5%和29.35 HV。进行先冷轧后时效后,当Gd含量为0.5wt%时,合金组织与性能最优,伸长率相比未先冷轧后时效的提高了50.1%。

       

      Abstract: The microstructure, melting performance and mechanical properties of Sn-43.5Bi-27Pb alloy with different Gd contents were studied using scanning electron microscopy(SEM), differential thermal analysis(DTA), and X-ray diffraction(XRD). The results show that the alloy contains three phases, namely Sn phase, Bi phase, and Pb7Bi3 intermediate phase. Its melting point is 96.5 ℃, the tensile strength is 55 MPa, and the elongation is 52.1%. The tensile strength of Sn-43.5Bi-27Pb-xGd(x=0.2, 0.5, 1.0, and 4.0) alloy is slightly lower than that of Sn-43.5Bi-27Pb low melting point alloy. When x=0.2, the phase composition of the alloy is the same as that of Sn-43.5Bi-27Pb alloy. When x =0.5 and x =1.0, the alloy has more Gd phases, while when x=4.0, the alloy has more Gd and Bi3Gd5 phases. As the Gd content increases, the melting range gradually narrows. When the Gd content is 1.0wt%, the microstructure and properties of the alloy are the best, with a minimum melting range of 12.72 ℃. Compared with Sn-43.5Bi-27Pb alloy, the melting range decreases by 2.48 ℃, and its tensile strength,elongation, and microhardness are 49 MPa, 47.5% and 29.35 HV, respectively. After cold rolling followed by aging, when the Gd content is 0.5wt%, the microstructure and properties of the alloy are optimal, and the elongation is increased by 50.1% compared with those without cold rolling followed by aging.

       

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