SAC305焊锡膏中抗氧化剂的筛选与评价

    Screening and Evaluation of Antioxidants in SAC305 Solder Paste

    • 摘要: 焊锡膏作为电子封装领域中不可或缺的材料,其性能直接影响焊点可靠性和封装质量。抗氧化剂作为焊锡膏的重要组成成分,能够防止焊锡膏中活性物质被氧化,对焊锡膏的性能具有重要影响。通过对焊锡膏及助焊膏的粘度、坍塌性、铺展性、色差等性能测试,探究抗坏血酸棕榈酸酯、叔丁基对苯二酚和二乙基二硫代氨基甲酸钠三种抗氧化剂对SAC305焊锡膏性能的影响,筛选出适用于SAC305焊锡膏的高效抗氧化剂。结果表明:加入3wt%的抗氧化剂后,助焊膏及焊锡膏粘度增加,且扩展率和铺展性均有所增加,但加入抗坏血酸棕榈酸酯和二乙基二硫代氨基甲酸钠导致焊点变黑、锡珠飞溅和热坍塌、桥连等问题。当选用叔丁基对苯二酚作为抗氧化剂时,其助焊膏及焊锡膏的粘度稳定性最优,扩展率最高,焊点形貌和润湿形貌最饱满,抗坍塌性最好,表面色差变化较小且不会出现发干等现象,是适合用于SAC305无铅焊锡膏的抗氧化剂。

       

      Abstract: As an indispensable material in the field of electronic packaging, the performance of solder paste directly affects the reliability and packaging quality of the solder joints. Antioxidant, as an important part of solder paste, can prevent the oxidation of active substances in solder paste, and has an important impact on its performance. The effects of ascorbyl palmitate(L-AP), tert-butylhydroquinone(TBHQ) and sodium diethyldithiocarbamate(DDTC) on the properties of SAC305solder paste were mainly explored by testing the viscosity, collapse performance, spreadability and chromatic aberration of flux and solder paste. Therefore, an effective antioxidant suitable for SAC305 solder paste was screened. The results show that after adding 3wt% antioxidants, the viscosity of flux and solder paste increases, the expansion rate and spreadability all increase. However, the addition of L-AP and DDTC produces some problems, such as blackening of solder joints, bead spatter, thermal collapse and bridge. When TBHQ is chosen as the antioxidant, the viscosity stability of the solder paste is optimum, the expansion rate is biggest, the solder joint morphology and the wetting morphology are plumpest, the collapse resistance is best, the surface chromatic aberration value is small, and the dry phenomenon doesn’t appear, which is suitable for the antioxidant of SAC305 lead-free solder paste.

       

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