不同制备工艺对CrFeNiAlSi高熵合金相及性能的影响

    Effects of Different Preparation Processes on Phase and Properties of CrFeNiAlSi High-entropy Alloy

    • 摘要: 采用激光烧结、真空熔炼及激光熔覆技术分别制备CrFeNiAlSi高熵合金与涂层,利用X射线衍射仪、激光共聚焦显微镜、扫描电镜、能谱扫描仪表征分析合金物相与微观组织结构,使用维氏硬度计、磨粒磨损机,研究了合金室温下的硬度以及磨损性能。结果表明:激光烧结CrFeNiAlSi(LS)合金和真空熔炼CrFeNiAlSi(VM)合金由BCC、FCC相组成,而激光熔覆CrFeNiAlSi(LC)涂层由单一BCC相组成。LS合金晶粒细小、均匀。LC涂层以胞状晶为主,晶界较宽,元素分布相对均匀。VM合金由树枝状枝晶和花瓣状枝晶组成,晶粒内为富Al相,晶界中为富Cr相。LC涂层表面硬度值最大,为875.1HV,单位面积磨损量为8.96mg·cm-2,其表面犁沟最浅,耐磨性最好。LS合金、VM合金表面硬度分别为803.3、820.4HV,单位面积磨损量分别为55.50、12.69mg·cm-2

       

      Abstract: Laser sintering, vacuum melting and laser cladding technologies were employed to prepare the Cr FeNiAlSi high-entropy alloy and coating, respectively. X-ray diffractometer, laser scanning confocal microscope, scanning electron microscope and energy spectrum scanner were used to characterize and analyze the alloy phase and microstructure. The hardness and wear performance of alloys at room temperature were studied using vickers hardness testers and abrasive wear machines. The results show that laser sintering Cr FeNiAlSi(LS) alloy and vacuum melting Cr FeNiAlSi(VM) alloy are composed of BCC and FCC phases, while the laser cladding Cr FeNiAlSi(LC) coating comprises a single BCC phase. The grains of LS alloy are fine and uniform. The LC coating is mainly composed of cellular crystals, with wide grain boundaries and relatively uniform element distribution. The VM alloy is composed of dendrites and petal-like dendrites. There are an Al-rich phase in the grain and a Cr-rich phase in the grain boundaries. The LC coating has the largest surface hardness of 875.1 HV, and the wear amount per unit area is 8.96 mg·cm-2. Its surface has the shallowest furrows and the best wear resistance. The surface hardness of LS alloy and VM alloy are 803.3 HV and 820.4 HV, respectively, and the wear amount per unit area is 55.50 mg·cm-2 and 12.69 mg·cm-2, respectively.

       

    /

    返回文章
    返回