纯锌和锌包钢在天津盐碱土中腐蚀行为研究

    Study on Corrosion Behavior of Pure Zinc and Zinc Clad Steel in Tianjin Saline-alkaline Soil

    • 摘要: 研究了塑性加工对纯锌和锌包钢在天津盐碱土中加速腐蚀20 d的腐蚀行为,采用失重法测定不同状态的纯锌和锌包钢的腐蚀动力学曲线。通过体视显微镜、SEM和XRD检测试样表面腐蚀产物的宏观形貌、微观形貌和成分。室内加速腐蚀20 d后,纯锌和锌包钢表面均形成了以ZnO为主,伴有少量Zn(OH)2的腐蚀产物。纯锌腐蚀速率由大到小的顺序依次为铸态锌棒、锌丝、一次热挤压锌棒、两次热挤压锌棒;锌包钢腐蚀速率大小顺序依次为挤压包覆锌包钢、热挤压锌包钢。挤压包覆锌包钢、热挤压锌包钢的电偶效应γ分别为1.398、2.671。塑性加工改善了纯锌和锌包钢在天津盐碱土中的耐蚀性能。

       

      Abstract: The corrosion behavior of pure zinc and zinc clad steel in Tianjin saline-alkaline soil for 20 d was investigated. The corrosion kinetics of pure zinc and zinc clad steel in different states were determined by using the mass loss method. The macroscopic morphology, microscopic morphology and composition of corrosion products on the sample surface were analyzed using XTT stereomicroscope, SEM and XRD, respectively. After 20 d of indoor accelerated corrosion, both pure zinc and zinc clad steel surfaces are mainly composed of ZnO, accompanied by some Zn(OH)2 corrosion products. The corrosion rate of pure zinc from highest to lowest is as follows: cast zinc rod, zinc wire, once hot extruded zinc rod, twice hot extruded zinc rod. The corrosion rate of zinc clad steel from highest to lowest is as follows: extrusion coated zinc clad steel and hot extruded zinc clad steel. The galvanic effect γ of the zinc clad steel is 1.398 for extrusion coated zinc clad steel and 2.671 for hot extruded zinc clad steel. Plastic processing effectively improves the corrosion resistance of both pure zinc and zinc clad steel in Tianjin saline-alkaline soil.

       

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