CO2注入井管柱腐蚀速率及服役寿命预测

    Corrosion Rate and Service Life Prediction of CO2 Injection Well String

    • 摘要: 随着碳捕集、利用与封存(carbon capture,utilization and storage,CCUS)技术在油田的持续应用,CO2腐蚀井下管柱现象引起高度重视,亟需适用于高CO2分压环境下考虑腐蚀速率随时间变化影响的腐蚀速率模型。通过模拟温度80~120℃、CO2分压15~30 MPa条件下Q125、3Cr和13Cr管材的腐蚀,建立了这3种管材考虑温度、CO2分压和腐蚀时间影响的腐蚀速率预测模型,并对Q125套管进行了安全服役寿命预测。结果表明:同一CO2分压下,Q125、3Cr管材腐蚀速率随温度增加呈先增后减的趋势,13Cr管材腐蚀速率随温度增加而增大;3种管材腐蚀速率均随CO2分压增加而增大。Q125管材匀速和变速两种腐蚀速率模型均适用,3Cr和13Cr管材适用变速腐蚀模型。Q125套管的抗拉安全服役年限随着CO2分压的增加而逐渐降低,抗拉安全服役年限最短约为12 a。

       

      Abstract: With the continuous application of CCUS technology in oil fields, the phenomenon of CO2corrosion of downhole string has attracted great attention, and it is urgent to apply the corrosion rate model considering the influence of corrosion rate change with time under high CO2partial pressure environment. By simulating the corrosion of Q125, 3Cr and13Cr pipes under the temperature of 80 ℃-120 ℃ and CO2partial pressure of 15 MPa-30 MPa, the three corrosion rate prediction models considering the influence of temperature, CO2partial pressure and corrosion time were established, and the safe service life of Q125 casing was predicted. The results show that under the same CO2partial pressure, the corrosion rates of Q125 and 3Cr pipes increase first and then decrease with the increase of temperature, and the corrosion rate of 13Cr pipe increases with the increase of temperature. The corrosion rates of the three pipes increase with the increase of CO2partial pressure. The uniform and variable speed corrosion rate models of Q125 pipe are applicable, and the variable speed corrosion model is suitable for 3Cr and 13Cr pipes. The tensile safe service life of Q125 casing gradually decreases with the increase of CO2partial pressure, and the shortest tensile safe service life is about 12 years.

       

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