低热裂、高强韧半固态压铸Al-Zn-Mg-Cu合金开发

    Development of Semi-solid Al-Zn-Mg-Cu Die Cast Alloy with Low Thermal Cracking, High Strength and Toughness

    • 摘要: 以Al-Zn-Mg-Cu合金为研究对象,通过成分设计、热裂评估及热处理工艺优化等方法,开发新型低热裂、高强高韧半固态铝合金材料。结合热力学计算和实验结果,探究不同组分对半固态铝合金成形性能、力学性能及组织演变的影响规律,获得了3种低热裂倾向的合金:Al4Zn6Mg2Cu、Al7Zn6Mg4Cu、Al10Zn6Mg2Cu。结果表明:通过优化的热处理制度(470℃/24 h+120℃时效24 h)使合金性能达到最佳。新型合金为T'和η'相双相强化模式,Zn/Mg比越高,合金中盘状η'相含量越高,球形T'相含量越低,球形相更有利于提高合金塑性。综合考量强度、硬度和塑性的值,确定Al4Zn6Mg2Cu合金具备最优的力学性能,其屈服强度、抗拉强度和伸长率分别达到421 MPa、473 MPa和9%。新型合金的力学性能明显优于半固态7075合金的。

       

      Abstract: Taking Al-Zn-Mg-Cu alloys as the research object, new semi-solid aluminum alloy materials with low thermal cracking, high strength and high toughness were developed through composition design, thermal cracking evaluation and heat treatment process optimization. Combined with thermodynamic calculations and experiments, the influence of different components on the forming properties, mechanical properties and microstructure evolution of semi-solid aluminum alloys was explored. Three alloys with low thermal cracking were obtained, i.e., Al4Zn6Mg2Cu, Al7Zn6Mg4 Cu and Al10Zn6Mg2 Cu.The results show that the best alloy performance is achieved by an optimized heat treatment system(470 ℃/24 h +120 ℃aging for 24 h). The new alloy employs a two-phase strengthening mode consisting of T' and η' phases. The bigger the Zn/Mg ratio, the higher the content of discoidal η' phase in the alloy, the lower the content of spherical T' phase. The spherical phase is more conducive to improving the alloy's plasticity. Based on the evaluation of strength, hardness and plasticity, it has been determined that the Al4Zn6Mg2 Cu alloy exhibits optimal mechanical properties. The yield strength, tensile strength and elongation of the alloy reach 421 MPa, 473 MPa and 9%, respectively. The mechanical properties of the alloy are significantly superior to those of the semi-solid 7075 alloy.

       

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