稳定化处理对Zn微合金化高Mg铝镁合金力学及腐蚀性能的影响

    Influence of Stabilization Treatment on Mechanical and Corrosion Properties of Zn Microalloyed High-Mg Aluminum-Magnesium Alloys

    • 摘要: 为开发高强韧耐腐蚀铝镁合金产品,系统研究了稳定化处理后的Al-6Mg与Al-6Mg-1Zn合金的微观结构、力学及腐蚀性能,并对其强韧化机制及腐蚀行为进行了分析。结果表明,Zn微合金化Al-6Mg合金经过稳定化处理后,硬度从132.95 HV上升到155.47 HV,抗拉强度从484 MPa提高至555 MPa,而伸长率只降低了0.8%。Zn的加入促进了细小T相(Mg32(Al,Zn)49)的析出,一方面抑制了位错的回复,为再结晶提供了驱动力;另一方面起到钉扎晶界的作用,有效阻碍了再结晶晶粒的生长。再结晶晶粒的细化、晶内密集的细小析出相,以及位错密度下降速度的减慢,共同优化了稳定化处理后Al-6Mg-1Zn合金的整体力学性能。此外,相较于稳定化处理后的Al-6Mg合金,相同状态下的Al-6Mg-1Zn合金具有更强的耐腐蚀性能,这主要归功于晶界处T相较β相(Al3Mg2)相的更大离散分布。

       

      Abstract: To advance the development of aluminum-magnesium alloy products with heightened toughness and corrosion resistance, the microstructure, mechanics and corrosion properties of Al-6 Mg and Al-6 Mg-1 Zn alloy were studied systematically, and the strength-toughness mechanism and corrosion behavior were analyzed. The results show that, after stabilizing of the Zn microalloying Al-6 Mg alloy, the hardness increases from 132.95 HV to 155.47 HV, the tensile strength increases from 484 MPa to 555 MPa, with a mere 0.8% reduction in elongation. The addition of Zn facilitates the precipitation of the fine T phase(Mg32(Al, Zn)49). This has a dual effect: firstly, impeding dislocation restitution and providing a driving force for recrystallization; secondly, acting as a grain boundary pinning agent, effectively impeding the growth of recrystallized grains. The refinement of recrystallized grains, coupled with the presence of dense, fine precipitated phases within the crystal lattice, and the slowing of the dislocation density, which synergistically optimize the overall mechanical properties of the stabilized Al-6 Mg-1 Zn alloy. Furthermore, in comparison to the stabilized Al-6 Mg alloy, the Al-6 Mg-1 Zn alloy in the same state has a stronger corrosion resistance. This enhancement primarily stemmes from the more extensive discrete distribution of the T phase, comparing with β phase(Al3 Mg2) along the grain boundaries.

       

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