固溶处理对AlCo1.2Cr0.8FeNi2.1共晶高熵合金组织和腐蚀性能的影响

    Effects of Solution Treatment on Microstructure and Corrosion Property of AlCo1.2Cr0.8FeNi2.1 Eutectic High Entropy Alloy

    • 摘要: 设计并使用真空中频熔炼炉制备了AlCo1.2Cr0.8FeNi2.1共晶高熵合金,研究了固溶处理对其微观组织和腐蚀性能的影响。利用XRD、SEM和EDS仪器表征了AlCo1.2Cr0.8FeNi2.1共晶高熵合金的晶体结构和微观组织,并使用电化学工作站测试了该合金在室温下3.5 wt%NaCl溶液中的腐蚀性能。结果表明,铸态AlCo1.2Cr0.8FeNi2.1高熵合金表现为由FCC相和B2相组成的典型共晶组织,经800 ℃×1 h固溶处理后合金未发生明显相变,有较好的高温稳定性。在900 ℃和1100 ℃固溶处理后出现针状析出相,在FCC中有富含Al和Ni元素的B2相析出。经1200 ℃固溶处理后,析出相消失,组织和元素分布更均匀。1200 ℃×1 h固溶处理后的合金拥有较高的腐蚀电位,较低的腐蚀电流密度和较大的极化电阻,表现出良好的耐蚀性能。

       

      Abstract: AlCo1.2Cr0.8FeNi2.1 eutectic high-entropy alloy (EHEA) was designed and prepared by vacuum medium frequency melting furnace, and the effect of solution treatment on its microstructure and corrosion properties was studied. The crystal structure and microstructure of AlCo1.2Cr0.8FeNi2.1 EHEA were characterized by XRD, SEM and EDS, and the corrosion properties of the alloys in 3.5 wt%NaCl solution at room temperature were tested by electrochemical workstation. The results show that the as-cast AlCo1.2Cr0.8FeNi2.1 EHEA exhibits a typical eutectic structure composed of FCC and B2 phases. After solution treatment at 800 ℃ for 1h, the alloy does not undergo obvious phase transformation and has good high temperature stability. However,needle-like precipitates appear in the alloy after solid solution treatment at 900 ℃ and 1100 ℃, and the B2 phase which is rich in Al and Ni elements precipitates in FCC phase. After heat treatment at 1200 ℃, the precipitated phase disappears, and the structure and element distribution are more uniform. Besides, the alloy after solution treatment at 1200 ℃ for 1 h has higher corrosion potential, lower corrosion current density and larger polarization resistance, showing the best corrosion resistance.

       

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