Y替代量对AB2型LaMgNi4系合金储氢性能的影响

    Effect of Y Substitution on Hydrogen Storage Performance of AB2-type LaMgNi4 Alloys

    • 摘要: 稀土AB2型合金普遍存在氢致非晶化现象。采用真空感应熔炼炉炼制了La1-xYxMg Ni3.8Al0.2x=0~0.4)合金,通过XRD、SEM、P-C-T储氢测试仪等设备对合金的相结构、显微组织和储氢性能进行测试及分析。结果表明:合金主要由LaMgNi4相和La(Ni Al)5相组成,当x≥0.1时,又出现了Ni3Y相。合金吸氢后为LaMgNi4H4.85和La0.91(Ni Al)5H4.43相,含Y合金中出现少量YH2相。铸态合金为针状组织,并且随着Y替代量的增多合金组织更加均匀,更加细化。Y的替代明显提高了合金的活化性能。313 K温度,3 MPa氢压下x=0、0.1、0.2、0.3、0.4的合金最大吸氢量分别为1.663wt%、1.656wt%、1.632wt%、1.635wt%和1.641wt%。x=0.1的合金的动力学性能最好,达到最大吸氢量的85.2%。合金的吸放氢焓变值ΔH随着Y含量增加而升高。x=0.3的合金的循环性能最好,在循环50次后,容量保持率在81.67%。

       

      Abstract: Hydrogen-induced-amorphization is prevalent in rare earth AB2-type alloys. La1-xYxMg Ni3.8Al0.2x=0-0.4) alloys were refined using a vacuum induction melting furnace, and the phase structure, microstructure and hydrogen sto rage properties of the alloys were tested and analyzed using XRD, SEM and P-C-T hydrogen storage tester. The results show that the alloy consists mainly of LaMgNi4 and La(NiAl)5 phases, with an additional Ni3Y phase appearing when x≥0.1. The alloys after hydrogenation consist of LaMgNi4H4.85and La0.91(Ni Al)5H4.43phases, with a small amount of YH2 phase occurring in the Y-containing alloy. The as-cast alloys are acicular structure and become more homogeneous and refined as the amount of Y substitution increases. Y substitution significantly improves the activation properties of the alloys. The maximum hydrogen uptake of the alloys with x=0, 0.1, 0.2, 0.3, and 0.4 at 313 K temperature and 3 MPa hydrogen pressure are 1.663 wt%, 1.656 wt%,1.63 2 wt%, 1.635 wt%, and 1.641 wt%, respectively. The alloy with x=0.1 has the best kinetics with 1 min hydrogen uptake reaching 85.2% of the maximum hydrogen uptake. The ΔH of the alloy increases with increase of Y content. The alloy with x=0.3 has the best cycling performance with capacity retention of 81.67% after 50 cycles.

       

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