53Cr21Mn9Ni4N耐热钢模铸坯碳化物析出规律研究

    Study on Carbide Precipitation Law of 53Cr21Mn9Ni4N Heat-Resistant Steel Mold Cast Blank

    • 摘要: 53Cr21Mn9Ni4N奥氏体耐热钢中碳化物的大小、分布和形态对材料的性能有重要影响,依托于某厂生产的53Cr21Mn9Ni4N模铸坯,采用光学显微镜、扫描电镜、夹杂物三维蚀刻仪、Thermo-Calc软件对其碳化物解析。结果显示,53Cr21Mn9Ni4N钢中主要存在两种类型碳化物相:一种是沿晶界析出的M23C6颗粒状碳化物,主要由Fe、Cr、C和Mn元素构成,其尺寸主要集中在2~10μm范围内;另一种是由γ相和M23C6构成的片层状碳化物,γ+M23C6型碳化物由交替排列的碳化物和奥氏体相构成,含有Fe、Cr、C、Mn、N元素,尺寸集中分布在10~50μm,从边部到心部,层状碳化物的等效直径、面积占比均呈增大的趋势,其中,碳化物的等效直径从边部的8.3μm增长到心部的33.6μm,面积占比从边部的6.70%增长到心部的32.07%,碳化物的长宽比集中分布在1.39~1.76。

       

      Abstract: The size, distribution and morphology of carbides in 53Cr21Mn9Ni4N austenitic heat-resistant steel have a significant impact on the material’s properties. Based on the 53Cr21Mn9Ni4N mold cast blanks produced by a certain factory,the carbides were analyzed using optical microscopy, scanning electron microscopy, three-dimensional etching instrument for inclusions, and Thermo-Calc software. The research results show that there are mainly two types of carbide phases in53Cr21Mn9Ni4N steel: one is the M23C6granular carbide precipitated along the grain boundaries, primarily composed of Fe,Cr, C and Mn elements, with the size mainly concentrated in the range of 2-10 μm; the other is the lamellar carbide formed by the γ phase and M23C6, consisting of alternating arrangements of carbides and austenite phases, containing Fe, Cr, C, Mn, N elements, with the size concentrated in the range of 10-50 μm. From the edge to the core, both the equivalent diameter and area percentage of the lamellar carbides show an increasing trend. Specifically, the equivalent diameter of the carbides grows from 8.3 μm at the edge to 33.6 μm at the core, and the area percentage increases from 6.70% at the edge to 32.07% at the core, with the aspect ratio of the carbides concentrated between 1.39 and 1.76.

       

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