高速激光熔覆NiCrAlY涂层的显微组织及其抗高温腐蚀/冲蚀性能

    Microstructure and High-temperature Flue Gas/Molten Salt Coupled Corrosion and Erosion Wear Behaviors of High Speed Laser Cladding NiCrAlY Coating

    • 摘要: 针对火电锅炉水冷壁表面严苛的高温腐蚀与冲蚀磨损问题,利用高速激光熔覆技术在15CrMo水冷壁管表面制备致密且无裂纹缺陷的NiCrAlY合金涂层。利用SEM、EDS、EBSD、XRD等表征方法对涂层的显微组织和力学性能进行表征,研究了涂层在模拟服役环境下的抗高温腐蚀及冲蚀磨损性能。结果表明,高速激光熔覆NiCrAlY合金涂层主要由γ-Ni、AlNi3以及少量的Al2Y4O9和Al5Y3O12组成;γ-Ni具有一定的取向特征,且沿沉积方向逐渐由平面晶向等轴晶转变,而其余相以晶内或晶界析出相的形式存在。高速激光熔覆涂层的硬度约为330.61 HV,明显高于水冷壁基材。在600℃,NiCrAlY涂层在192 h后的高温腐蚀增重比基材降低约90.5%,而高温冲蚀体积损失降低约60.1%。高速激光熔覆涂层具有优异的抗高温烟气/熔盐耦合腐蚀性能和抗高温固态颗粒冲蚀磨损性能,可用于锅炉水冷壁表面防护涂层的使用。

       

      Abstract: Aiming at the severe high-temperature corrosion and erosion wear problems on the surface of the water wall in thermal power boilers, high-speed laser cladding technology was used to prepare dense NiCrAlY alloy coating without cracks on the surface of 15 CrMo water wall pipes. SEM, EDS, EBSD, XRD and other characterization methods were used to characterize the microstructure and mechanical properties of the coating, and then the high temperature corrosion resistance and impact wear properties of the coating were tested in the simulated service environment. The results show that the NiCrAlY coating is mainly composed of γ-Ni, AlNi3 and tiny Al2Y4O9 and Al5Y3O12. γ-Ni grains show orientation characteristics in some degree, and gradually change from the planar to equiaxed grains along the deposition direction. The rest phases mainly precipitate inside the grain and along the boundaries. The hardness of the high-speed laser cladding NiCrAlY coating is about 330.61 HV, which is significantly higher than that of 15CrMo substrate. At 600 ℃, the high-temperature corrosion weight gain of NiCrAlY coating after 192 h is about 90.5% lower than that of the substrate,and the high-temperature erosion volume loss is about 60.1% lower. The high-speed laser cladding coating has excellent resistance to high-temperature flue gas/molten salt coupled corrosion and high-temperature solid particle erosion wear, which is potential in the application of protective coating on the surface of boiler water wall.

       

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