连续氧化铝纤维表面化学镀镍工艺探究

    Study on Electroless Nickel Plating Process on Surface of Continuous Alumina Fiber

    • 摘要: 氧化铝纤维(Al2O3f)具有高强度、耐腐蚀、耐高温等优异的性能,对我国国防装备及国民重大经济产业提升具有重要战略意义,被广泛用做金属基复合材料中的增强相。但氧化铝纤维与金属基体间的浸润性差,使金属基复合材料性能的提升受到限制。在氧化铝纤维表面施镀金属涂层,可以有效地提高Al2O3f与基体之间的浸润性,同时赋予其特殊的电学、磁学等性能,扩宽氧化铝纤维的应用领域。本研究采用化学镀方法在连续氧化铝纤维表面成功制备了均匀完整的镍镀层,运用扫描电子显微镜、X射线能谱仪,对镀镍纤维表面形貌及元素组成进行分析,并结合镀后纤维增重率、单位电阻值,对比分析了各因素对镍镀层质量的影响。结果表明:化学镀镍纤维具有明显的皮-心结构(Al2O3f@Ni),即表层为完整的金属镍镀层,内部为Al2O3f;实验条件下,当硫酸镍为35 g/L、次亚磷酸钠为25 g/L、柠檬酸钠为30 g/L、氯化铵为20 g/L、化学镀工作温度为75℃时制备的金属镀层质量最好,增重率高达30 wt%,单位电阻值低至0.8Ω/cm。

       

      Abstract: Continuous alumina fiber(Al2O3f), known for their high strength, corrosion resistance and high-temperature tolerance, holds significant strategic importance for the enhancement of China’s national defense equipment and major economic industries. It is widely used as a reinforcing phase in metal matrix composites(MMCs). However, the poor wettability between alumina fiber and metal matrix limits the improvement of the properties of metal matrix composites. The application of a metal coating on the surface of alumina fiber can effectively improve the wettability between Al2O3fand the matrix, and endows it with special electrical and magnetic properties, which broadens the application field of alumina fiber. In this study, a uniform and complete nickel coating was successfully prepared on the surface of continuous alumina fiber by electroless plating. The surface morphology and elemental composition of nickel-plated fiber were analyzed by scanning electron microscopy and X-ray energy dispersive spectrometer. Combined with the weight gain rate and unit resistance value of the plated fiber, the effects of various factors on the quality of nickel coating were compared and analyzed. The results show that the coating fiber has an obvious core-shell structure(Al2O3f@Ni), with an outer layer of intact metallic nickel plating and an inner core of Al2O3f. Under the experimental conditions, the best quality metal plating is achieved with nickel sulfate at 35 g/L, sodium hypophosphite at 25 g/L, sodium citrate at 30 g/L, ammonium chloride at 20 g/L, and the system temperature 75℃. The weight gain rate is as high as 30 wt%, and the unit resistance is as low as 0.8 Ω/cm.

       

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