TA0和TA1在熔融软钎料中的耐蚀性研究

    Study on Corrosion Resistance of TA0 and TA1 in Molten Soft Solders

    • 摘要: 钛及钛合金具有优良的耐蚀性和耐高温性,被广泛应用于波峰焊设备的叶轮和炉胆。基于静态和动态钎料腐蚀实验,研究了TA1和TA0在250 ℃ Sn37Pb钎料和300 ℃ SAC305钎料中的耐蚀性。电化学极化曲线和交流阻抗测试结果表明,TA0的自腐蚀电流密度更低和容抗弧的半径更大,TA0的钝化膜更为致密稳定。在静态熔融的250 ℃ Sn37Pb钎料中TA1的腐蚀速率更大,TA0的耐蚀性优于TA1,主要原因在于TA0中的O含量更低和钝化膜更稳定。在300 ℃静态熔融SAC305钎料中TA0的腐蚀速率更小,抗钎料腐蚀能力更强,主要原因在于TA0的Fe含量更低,FeSn2 生成量更少。在动态SAC305钎料腐蚀实验中,样品转速的增大会加速钛合金的腐蚀,由于受到钎料的冲刷腐蚀,动态钎料中钛合金的腐蚀速率高于静态钎料,而且TA0的腐蚀速率小于TA1的,耐腐蚀性能更好。

       

      Abstract: Titanium and titanium alloys have excellent corrosion resistance and high temperature resistance, and are widely used in impellers and furnaces of wave soldering equipment. The corrosion resistance of TA1 and TA0 in 250 ℃ Sn37Pb soft solder and 300 ℃ SAC305 soft solder was studied based on static and dynamic brazing metal corrosion experiments. The electrochemical polarization curve and AC impedance test results show that the self-corrosion current density of TA0 is lower and the radius of capacitive arc is larger, and the passivation film of TA0 is more dense and stable. The corrosion rate of TA1 in the static molten 250 ℃ Sn37Pb brazing metal is larger, and the corrosion resistance of TA0 is better than that of TA1, mainly due to the lower O content in TA0 and more stable of the passivation film. In the static molten SAC305 brazing metal at 300 ℃, the corrosion rate of TA0 is smaller, and the corrosion resistance to the brazing metal is stronger, mainly due to the lower Fe content of TA0 and the lower generation content of FeSn2. In the dynamic SAC305 brazing metal, the increase of the rotational speed accelerates the corrosion of titanium alloy, due to the erosion and corrosion of the brazing metal, the corrosion rate of titanium alloys in the dynamic brazing metal is higher than that of the static brazing metal. The corrosion rate of TA0 is less than that of TA1, and the corrosion resistance is better.

       

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