镀锌10Mn钢高温拉伸中的液态金属致脆失效行为研究

    Liquid Metal Embrittlement Behavior of Galvanized 10Mn Steel During High Temperature Tensile Test

    • 摘要: 以1.4 mm厚的镀锌10Mn钢为研究对象,基于Gleeble 3500热模拟试验机研究其在不同拉伸温度(500~1000℃)、拉伸应变速率(10-3~1 s-1)和保温时间(0~320 s)作用下的液态金属致脆(liquid metal embrittlement,LME)失效行为。研究表明,当应变速率为1、10-1、10-2 s-1时,10Mn中锰钢发生LME的温度范围分别为700~950℃、700~950℃和800~950℃;即随着应变速率的降低,发生LME的起始温度变高,温度窗口变窄;应变速率降低至10-3 s-1时,未发生LME现象。随着保温时间的延长,镀锌10Mn钢的塑性逐渐恢复,800℃保温240 s以上可使钢板表面镀锌层与钢板基体反应生成α-Fe(Zn)固溶体层从而消除LME现象。对镀锌10Mn钢高温拉伸裂纹处进行SEM、EDX和EBSD分析,结果表明受液锌浸润发生LME的10Mn钢断裂表面为脆性断裂,没有与液态锌接触的10Mn钢断口为韧性断裂,LME裂纹内部存在锌元素并沿晶界扩展。

       

      Abstract: Liquid metal embrittlement (LME) of a 1.4 mm-thick galvanized 10Mn steel was investigated using a Gleeble 3500 thermal simulation tester. The fracture mode and failure behavior of galvanized 10Mn steel under different tensile temperatures (500 ℃-1000 ℃), tensile strain rates (10-3 s-1 -1 s-1) and holding time (0 s-320 s) were analyzed. It is found that when the strain rates are 1 s-1, 10-1 s-1 and 10-2 s-1, the temperature ranges of LME in 10Mn medium manganese steel are 700 ℃-950 ℃, 700 ℃-950 ℃ and 800 ℃-950 ℃, respectively. With the decrease of strain rate, the starting temperature of LME became higher and the temperature window become narrower. When the strain rate is reduced to 10-3 s-1, the LME does not occur. With the extension of holding time, the plasticity of galvanized 10Mn steel gradually recovers, and the LME can be eliminated by holding at 800 ℃ for 240 s and more, for the reason that the zinc layer reacts with the steel plate matrix and forms α-Fe(Zn) solid solution layer. SEM, EDX and EBSD analysis show that the fracture surface produced in contact with liquid zinc presents a typical brittle fracture surface, while the fracture surface without contact with liquid zinc is a dimple surface typical of ductile fracture. There is zinc distribution in the cracks tips and most of the cracks propagates along grain boundaries.

       

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