反应温度和时间对原位反应制备Al3Ti/Al基复合材料的影响

    Effects of Reaction Temperature and Time on Preparation of Al3Ti/Al Matrix Composites by In-situ Reaction

    • 摘要: 选用纯度99.00wt%的金属铝为基体,40目钛丝网为反应源,采用热压装置通过原位反应法在不同工艺条件下制备出Al3Ti颗粒增强Al基复合材料。结果表明:随反应温度升高,时间增长,原位反应越充分。原位反应机理为铝原子迁移通过钛边界层,经过扩散到达生成物层,此时发生反应得到Al3Ti;同时固-液界面前沿不断推进,使活性钛原子进入铝液,Al3Ti晶粒进一步生长、长大。得到的最佳反应条件为反应温度850℃、保温1 h、压力为12 MPa。在此条件下,获得的复合材料显微硬度是铝基体的10倍,复合材料的磨损率为单纯铝基体磨损率的1/5。原位反应制备Al3Ti/Al基复合材料的强化机理主要包括颗粒强化、位错强化和弥散强化的共同作用。

       

      Abstract: Al3Ti particle reinforced Al matrix composite under different process conditions were prepared by using hot pressing device through in-situ reaction with 99.00wt% aluminum metal as substrate and titanium wire with 40 mesh as reaction source. The results show that, with the increase of the reaction temperature and time, the in-situ reaction becomes more adequate. The mechanism of in-situ reaction is that aluminum atoms migrate through the titanium boundary layer then diffuse to the product layer and react and form Al3Ti. At the same time, the front of the solid-liquid interface keeps advancing,and the active titanium atoms are pushed into the aluminum solution, and Al3Ti grains further grow. The optimum reaction conditions are as follows: reaction temperature of 850 ℃, heat preservation for 1 h and pressure of 12 MPa. Under these conditions, the microhardness of the composite is 10 times of that of the aluminum matrix, and the wear rate of the composite is 1/5 of that of the pure aluminum matrix. The strengthening mechanism of Al3Ti/Al matrix composites prepared by in-situ reaction mainly includes particle strengthening, dislocation strengthening and dispersion strengthening.

       

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