高强韧15Cr不锈钢H2S和CO2腐蚀行为研究

    Study on H2S and CO2 Corrosion Behavior of High Strength and Toughness 15Cr Stainless Steel

    • 摘要: 通过硫化物应力开裂(SSC)、应力腐蚀开裂(SCC)试验、高温高压失重腐蚀模拟试验以及原位电化学测试,研究了抗硫型高强韧15Cr不锈钢在H2S和CO2生产工况环境中的腐蚀行为。结果表明:在NACE TM0177标准条件下(B溶液)和模拟工况条件下(90℃,3 MPa CO2,2 kPa H2S),高强韧15Cr不锈钢的SSC和SCC敏感性较低,展现出优异的抗硫化氢应力腐蚀开裂性能。在超高温、超高CO2和低H2S分压条件下,高强韧15Cr表现出良好的抗均匀腐蚀和局部腐蚀性能。相较于CO2和H2S分压,温度对腐蚀速率的影响程度更显著,其适用温度可达220℃(均匀腐蚀速率为0.09 mm/a,无明显点蚀)。在模拟工况条件下,高强韧15Cr表面形成p-n型双极性钝化膜,相比于超级13Cr,具有较低的掺杂浓度(NA=7.95×1022cm-3,ND=1.87×1022cm-3)、较高的点蚀保护电位(Ep=-148 mV)和极化电阻(Rp=6048.69Ω·cm2),耐蚀性更高。本研究成果为高强韧15Cr不锈钢在H2S和CO2环境中使用提供了理论依据。

       

      Abstract: The corrosion behavior of high-strength and toughness 15 Cr stainless steel under H2S and CO2 production conditions was studied by sulfide stress cracking(SSC), stress corrosion cracking(SCC) tests, high temperature and high pressure corrosion simulation tests and in-situ electrochemical tests. The results show that under NACE TM0177 standard conditions(B solution) and simulated working conditions(90 ℃, 3 MPa CO2, 2 kPa H2S), the SSC and SCC sensitivity of high-strength and toughness 15 Cr stainless steel are low, showing excellent resistance to hydrogen sulfide stress corrosion cracking. Under the conditions of ultra-high temperature, ultra-high CO2 and low H2S partial pressure, the high strength and toughness 15 Cr exhibits good resistance to uniform corrosion and local corrosion. Compared with the partial pressure of CO2 and H2S, the influence of temperature on the corrosion rate is more significant, and its applicable temperature can reach 220 ℃(with a uniform corrosion rate of 0.09 mm/a and no obvious pitting corrosion). Under simulated conditions, p-n bipolar passivation film is formed on the surface of high-strength and toughness 15 Cr. Compared with Super 13 Cr, it has lower doping concentration(NA=7.95×1022cm-3, ND=1.87×1022cm-3), higher pitting protection potential(Ep=-148 mV), and polarization resistance(Rp=6048.69 Ω ·cm2), and higher corrosion resistance. The research results provide a theoretical basis for the use of high strength and toughness 15Cr stainless steel in H2S and CO2 environment.

       

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