增强相预氧化对激光粉末床熔融SiC/AlSi10Mg复合材料微观组织及力学性能的影响

    Effect of Reinforcement Pre-oxidation on Microstructure and Mechanical Properties of Laser Powder Bed Fused Si C/AlSi10Mg Composites

    • 摘要: 在铝基复合材料领域中,SiC是一种常用的增强相颗粒,但其表面通常会有较高的表面能,直接使用SiC颗粒作为增强相难以充分发挥其性能强化效果,因此,需要对SiC进行预处理工作。系统研究了粉末高温氧化预处理对选择性激光熔化成形SiC/AlSi10Mg复合材料微观组织与力学性能的影响。通过对比未处理、SiC高温氧化处理的两种复合材料物相组成、致密性、晶粒取向及力学行为,揭示处理工艺对材料性能的调控机制。结果表明,SiC颗粒经高温氧化后表面生成SiO2薄膜,显著抑制了SiC与熔融Al基体的有害界面反应(生成Al4SiC4相),减少孔隙率并降低应力集中,使复合材料的抗压强度提升至584.7 MPa,抗拉强度达到424.6 MPa,伸长率达到5.2%。未预处理的复合材料抗压强度仅为574.5 MPa,抗拉强度为397.2 MPa,伸长率为1.8%。SiC颗粒氧化抑制了SiC与熔融Al基体的原位反应,从而抑制共晶硅粗化、减少微孔缺陷,协同增强了界面结合强度与位错钉扎效应。本研究为高强韧铝基复合材料的SLM成形工艺优化提供了理论依据与实验支撑。

       

      Abstract: In the field of aluminum matrix composites, Si C is a commonly used reinforcing phase particle, but its surface usually has a high surface energy, and it is difficult to give full play to its performance enhancement effect on the matrix by directly using Si C particles as the reinforcing phase, so pretreat work is usually necessary for Si C. The effects of powder pretreatment process of high temperature oxidation on the microstructure and mechanical properties of selective laser melting(SLM)-fabricated Si C/Al Si10Mg composites were systematically investigated. By comparing phase composition,densification, grain orientation, and mechanical behavior between untreated and high-temperature-oxidized Si C specimens,the regulatory mechanisms of pretreatment on the material performance were elucidated. The results show that the SiO2 film formed on oxidized Si C particles effectively suppresses detrimental interfacial reactions(e.g., Al4Si C4 phase formation) between Si C and molten Al matrix, reduces porosity, and mitiga tes stress concentration. Consequently, the preoxidized composite achieves enhanced compressive strength of 584.7MPa, tensile strength of 424.6 MPa and elongation of 5.2%,while the those of the composite are 574.5 MPa, 397.2 MPa and 1.8%, respectively. The oxidation of Si C particles inhibits the in-situ reaction between SiC and molten Al matrix, therefore inhibits the eutectic Si coarsening and reduces the microvoid defects. This work provides theoretical and experimental foundations for optimizing SLM-processed high-strength aluminum matrix composites.

       

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