增材制造纯钛的磨损与腐蚀磨损各向异性研究

    Study on Wear and Tribocorrosion Anisotropy of Additive Manufactured Pure Titanium

    • 摘要: 采用激光粉末床熔融制备纯钛试样,构建方向分别为与基板平面呈0°、30°、45°、60°和90°,研究了纯钛样品的微观组织、干磨损和腐蚀磨损性能。结果表明:随着构建方向与基板平面夹角的增大,微观结构由等轴晶与针状马氏体α'的混合结构→锯齿状、针状马氏体α'→沿构建方向的细长马氏体α'转变,导致晶界密度降低以及施密特因子偏差增大。在干磨损试验过程中,犁沟磨损和氧化磨损是主要的磨损机制,而在Hank's溶液中,塑性变形为主要磨损机制。Hank's溶液有效地降低了磨损系数并减轻了高温氧化,但同时会诱发腐蚀坑的形成,从而加速磨损。施密特因子偏差、晶界密度以及平均晶粒的各向异性,是增材制造纯钛干磨损以及腐蚀磨损各向异性的原因。

       

      Abstract: Pure titanium samples were prepared by laser powder bed melting, and the building directions were 0°, 30°,45°, 60° and 90° to the substrate plane, respectively. The microstructure and dry wear/corrosion wear resistance of pure titanium specimens were studied. The results show that with the increase of the angle between the building direction and the substrate plane, the microstructure changes are as follows:the mixed structure of equiaxed grains and acicular-shape martensite α’→ zig-zag and acicular-shaped martensite α’→ slender martensite α’ along the building direction, which results in the decrease of the grain boundary density and the increase of the deviation of Schmidt factor. In the dry wear test, furrow wear and oxidation wear are the main wear mechanisms, while in Hank’s solution, the plastic deformation is the main wear mechanism. Hank’s solution effectively reduces the wear coefficient and high-temperature oxidation, but at the same time it induces the formation of corrosion pits, thereby accelerating wear. Schmitt factor deviation, grain boundary density and average grain anisotropy lead to the wear and corrosion wear anisotropy of pure titanium in additive manufacturing.

       

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