电渣重熔含镧GH2984高温合金镧烧损热力学分析

    Thermodynamic Analysis of La Burning Loss of La-containing GH2984 Superalloy by Electroslag Remelting

    • 摘要: 为研究含稀土镧GH2984高温合金电渣重熔过程中渣系各组元对合金中稀土镧的影响,基于离子-分子共存理论,建立计算了CaF2-CaO-Al2O3-MgO-TiO2-La2O3质量作用浓度(活度)的热力学模型,并进行了实验验证。结果表明:在1500~1700℃下,合金中的La可以与熔渣中的Al2O3和TiO2发生反应,且温度越低,La的烧损越大。随渣中CaF2、Al2O3、TiO2含量增加,La2O3活度降低,合金中La烧损加剧;随渣中CaO、La2O3和MgO含量增加,La2O3活度增加,La烧损减少。随渣中Al2O3含量从18.37wt%增加到24.76 wt%,合金中La收得率从18.4%降低到12.2%。随渣中La2O3含量从4.28wt%提高到10.49wt%,合金中La收得率从12.2%提高到23.0%。

       

      Abstract: In order to study the effect of slag components on rare earth La in GH2984 superalloy containing rare earth La during electroslag remelting, a thermodynamic model for calculating the mass action concentration (activity) of CaF2-CaO- Al2O3-MgO-TiO2-La2O3 was established based on the ion-molecule coexistence theory(IMCT), and the experimental verification was carried out. The results show that La in the alloy can react with Al2O3 and TiO2 in the slag at 1500 ℃-1700 ℃, and the lower the temperature, the greater the burning loss of La. With increase of the content of CaF2, Al2O3 and TiO2 in the slag, the activity of La2O3 decreases, and the burning loss of La in the alloy increases. With the increase of the content of CaO, La2O3 and MgO in the slag, the activity of La2O3 increases, and the burning loss of La decreases. With the content of Al2O3 in the slag increase from 18.37wt% to 24.76wt%, and the yield of La in the alloy decreases from 18.4% to 12.2%. With the content of La2O3 in the slag increases from 4.28wt% to 10.49wt%, and the yield of La in the alloy increases from 12.2% to 23.0%.

       

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