铜表面WC/Ni60A耐磨熔覆层的组织与性能研究

    Study on Microstructure and Properties of WC/Ni60A Wear-resistant Cladding Layer on Copper Surfaces

    • 摘要: 为了提高铜表面的抗磨损性能,利用等离子熔覆技术在其表面制备了15wt%WC/Ni60A复合涂层,系统研究了涂层的微观结构、显微硬度、高温耐磨性以及传热特性。结果表明:等离子熔覆方法制备的WC/Ni60A复合涂层光滑平整,没有裂纹缺陷,能够与铜基体形成扩散冶金结合。涂层中形成了大量WC、Cr B、Cr23C6等陶瓷增强相,并弥散分布在γ-(Cu, Fe, Ni)固溶体中,致使其平均显微硬度是纯铜的12倍。此外,复合涂层在600℃下的耐磨性比纯铜在300℃下的耐磨性还要高出约4倍,这得益于其较强的抗氧化性和抗塑性变形能力。温度场模拟结果表明,铜表面熔覆WC/Ni60A涂层后,表面工作温度有所上升,但仍在涂层保持良好耐磨性的温度范围内。此研究结果可为冶金铜部件的表面强化提供理论指导。

       

      Abstract: To improve the wear resistance of copper surface, 15 wt% WC/Ni60A composite coating was prepared on its surface by plasma cladding technology. The microstructure, microhardness, high-temperature wear resistance and heat transfer characteristics of the coating were systematically studied. The results show that the coating prepared by plasma cladding method is smooth and flat, without crack defects and can form a diffusion metallurgical bonding with the copper substrate. A large number of ceramic reinforcements such as WC, Cr B and Cr23C6 are formed in the coating and dispersed in the γ-(Cu, Fe,Ni) solid solution, resulting in an average microhardness of about 12 times than that of pure copper. In addition, the wear resistance of composite coating at 600 ℃ was about 4 times higher than that of pure copper at 300 ℃, which is due to its strong oxidation resistance and plastic deformation resistance. Temperature field simulation results show that the surface working temperature increases after cladding WC/Ni60A coating on copper surface, but it is still within the temperature range where the coating maintains good wear resistance. The results of this study can provide theoretical guidance for the surface strengthening of metallurgical copper components.

       

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