激光熔覆高熵合金涂层研究现状

    Research Status on Laser Cladded High Entropy Alloy Coatings

    • 摘要: 激光熔覆具有加热与冷却速率快、涂层与基体结合强度高、稀释率低以及工艺适用范围广等优点。高熵合金凭借四大核心特征效应(热力学中的高熵效应、结构上的晶格畸变效应、动力学的缓慢扩散效应、性能上的“鸡尾酒”效应)而具备优异的综合性能,因此常应用于激光熔覆中。系统综述了激光熔覆高熵合金涂层的最新发展动态:通过优化激光工艺参数可影响微观组织与性能,从而提高涂层的成型质量;热处理、超声振动和磁场辅助等辅助工艺能有效抑制气孔和裂纹的产生;添加硬质陶瓷相和稀土元素可显著增强涂层的硬度、耐磨性和耐蚀性;合金成分设计逐步从等摩尔比向非等摩尔比方向发展。最后,针对激光熔覆高熵合金涂层理论预测和模拟研究的不足,提出智能化(机器学习、数字孪生)和极端环境应用等未来发展方向。

       

      Abstract: Laser cladding has the advantages of fast heating and cooling rates, high bonding strength between the coating and substrate, low dilution rate, and wide applicability of the process. High entropy alloys are widely applied in laser cladding due to their exceptional comprehensive properties, which stems from four core characteristic effects: the high entropy effect in thermodynamics, lattice distortion effect in structure, sluggish diffusion effect in kinetics, and the "cocktail" effect in performance. The latest developments in laser cladded high entropy alloy coatings are systematically reviewed. The optimization of laser processing parameters can effectively influence microstructures and properties, thereby enhancing the coating formation quality. Auxiliary processes such as heat treatment, ultrasonic vibration and magnetic field assistance can effectively suppress porosity and cracks. Adding hard ceramic phases and rare earth elements can significantly enhance the hardness, wear resistance, and corrosion resistance of coatings. Alloy composition design progressively evolves from equimolar ratios to non-equimolar configurations. Finally, in order to address the current limitations in theoretical prediction and simulation of laser cladded HEA coatings, the future research directions emphasizing intelligent approaches (machine learning, digital twins) and extreme environment applications were proposed.

       

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