低铼二代单晶高温合金DD515的热处理工艺、组织和性能研究

    Study on Heat Treatment Process, Microstructure and Properties of Low Re Second-generation Single Crystal Superalloy DD515

    • 摘要: 针对二代单晶高温合金铼成本高的问题,以低铼单晶DD515为试验材料、DD5合金为对照,采用定向凝固制备单晶试样,结合光学显微镜、场发射扫描电子显微镜、差示扫描量热法、高温力学测试、1100℃静态氧化试验,研究热处理工艺对DD515合金组织与性能的调控规律。结果表明:DD515合金在铸态下存在明显的元素偏析,其共晶含量较DD5合金增加了约2.9%。DD515合金的初熔温度范围为1290~1295℃。随固溶温度从1285℃提高到1300℃、保温时间从2 h延长到4 h,合金中残余共晶含量减少,微孔体积分数增加。1295℃/2 h空冷+1080℃/4 h空冷+900℃/4 h空冷为最优热处理工艺,该工艺下γ'相的平均尺寸约为0.313 μm,体积分数为60%~70%,合金与870℃拉伸性能DD5持平,1093℃/158 MPa持久寿命最优,1100℃抗氧化能力与DD5相当。综合组织缺陷、工艺成本与服役性能,推荐DD515采用1285~1295℃保温2 h单步固溶,配套双级时效工艺,为该低成本单晶合金工程化应用提供数据支撑。

       

      Abstract: To address the high cost of rhenium in second-generation single-crystal superalloys, low-rhenium single- crystal alloy DD515 was selected as the experimental material with DD5 alloy as the control group. Single-crystal specimens were fabricated via directional solidification. Combined with optical microscopy, field-emission scanning electron microscopy, differential scanning calorimetry, high-temperature mechanical property tests and isothermal oxidation tests at 1100 ℃, the regulation law of heat treatment processes on the microstructure and properties of the DD515 alloy was investigated. Significant elemental segregation occurs in the as-cast DD515 alloy, whose eutectic content is approximately 2.9% higher than that of DD5 alloy. The initial melting temperature range of DD515 alloy is 1290 ℃-1295 ℃. As the solution temperature rises from 1285 ℃ to 1300 ℃ and the holding time extends from 2 h to 4 h, the volume fraction of residual eutectics in the alloy decreases, while the volume fraction of micropores increases correspondingly. The optimal heat treatment regime consists of solution treatment at 1295 ℃ for 2 h with air cooling, followed by two-stage aging at 1080 ℃ for 4 h(air cooling) and 900 ℃ for 4 h(air cooling). Under this treatment, the average size of the γ' phase is approximately 0.313 μm with a volume fraction ranging from 60% to 70%. The alloy exhibits tensile properties at 870 ℃ compare to DD5 alloy, achieves the maximum stress rupture life at 1093 ℃ under 158 MPa, and possesses oxidation resistance at 1100 ℃ equivalent to that of DD5 alloy. Considering the microstructure defects, process cost and service performance comprehensively, a single-step solution treatment at 1285 ℃-1295 ℃ for 2 h combined with two-stage aging is recommended for DD515 alloy. This work provides data support for the engineering application of the low-cost single-crystal superalloy.

       

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